Asymmetric approaches to 1,2-disubstituted mitosenes based on the intramolecular cyclization of diazoesters
A strategy for the asymmetric synthesis of 1,2-disubstituted mitosenes is described. The key reaction is the decomposition of a meso diazoester in the presence of chiral copper(I) catalysts. Cyclization of diazoesters derived from (1R, 2S, 5R)-menthol and
Lee, Sangku,Lim, Hee-Jong,Cha, Kobpurn Lulu,Sulikowski, Gary A.
p. 16521 - 16532
(2007/10/03)
Enantioselective Synthesis of a 1,2-Disubstituted Mitosene by a Copper-Catalyzed Intramolecular Carbon-Hydrogen Insertion Reaction of a Diazo Ester
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Lim, Hee-Jong,Sulikowski, Gary A.
p. 2326 - 2327
(2007/10/02)
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