cas 16413-75-5, N-(β-Hydroxy-α-methylphenethyl)-N-methylacetamide | Articles data ｜lookchem

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16413-75-5

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MISE EN EVIDENCE PAR RMN-(1)H ET -(13)C D'ISOMERISME Z/E ET D'EQUILIBRE CONFORMATIONNEL SUR UNE SERIE DE DERIVES MONO- ET DIACETYLES DE 2-ALKYLAMINO-1-PHENYLPROPAN-1-OLS
(1)H- and (13)C NMR studies of mono- and diacetylated-erythro- and threo-2-alkylamino-1-phenylpropan-1-ols, C6H5CHOHCHNHRCH3 (R = H, CH3, C2H5 AND i-C3H7) show that the series exhibit Z/E isomerism about the C-N amide bond.The Z/E ratio increases in the monoacetylated series CH3 1-C2 and N-C2 bonds.In the Z configuration, the conformer Z-s-syn where the proton H-2 is syn with the N-alkyl substituent predominates.
Tytgat, D.,Gelbcke, M.
p. 479 - 490
(2007/10/02)

REACTION OF 1-(p-NITROPHENYL)-2-ACETYLAMINO-1,3-PROPANEDIOL WITH SODIUM HYPOCHLORITE
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Zhestkov, V. P.,Voronin, V. G.,Portnov, Yu. N.
p. 657 - 660
(2007/10/02)

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Chemical Properties

Boiling Point: 361.2°Cat760mmHg
Flash Point:172.3°C
Density: 1.083g/cm³
Vapor Pressure: 7.53E-06mmHg at 25°C
PSA: 40.54000
LogP: 1.58680

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