165262-94-2Relevant articles and documents
One-pot synthesis of cage alcohols
Klimochkin, Yu. N.,Yudashkin,Zhilkina,Ivleva,Moiseev,Oshis, Ya. F.
, p. 971 - 976 (2017/09/07)
An efficient one-pot procedure has been developed for the synthesis of cage alcohols with hydroxy groups in the bridgehead positions. The procedure includes initial nitroxylation with nitric acid or a mixture of nitric acid with acetic acid and subsequent hydrolysis in the presence of urea.
Reaction Of The 3-R-1-Adamantyl Radical With Tetranitromethane
Medzhinskii, V. L.,Golod, E. L.
, p. 741 - 745 (2007/10/02)
The 3-R-1-adamantyl radicals, obtained by the thermolysis of tert-butyl 3-R-1-adamantanepercarboxylates, react with tetranitromethane to form 3-R-1-(trinitromethyl)adamantanes.Reduction of the latter with hydrogen peroxide in an alkaline medium gives 3-R-
REACTION OF MONOFUNCTIONAL SUBSTITUTED ADAMANTANES WITH NITRIC ACID AND ITS MIXTURES
Moiseev, I. K.,Klimochkin, Yu. N.,Zemtsova, M. N.,Trakhtenberg, P. L.
, p. 1307 - 1309 (2007/10/02)
In the reaction of monofunctional substituted adamantanes with nitric acid and its mixtures the main reaction products are the nitrates of adamantanol, formed either as a result of substitution of the functional groups or as a result of substitution of a hydrogen atom at a tertiary carbon atom.
