165544-13-8

Basic information

• Product Name: Ethanone, 1-(2-methyl-1,3-dioxan-2-yl)- (9CI)
• Synonyms: Ethanone, 1-(2-methyl-1,3-dioxan-2-yl)- (9CI)
• CAS NO: 165544-13-8
• Molecular Formula: C₇H₁₂O₃
• Molecular Weight: 144.16838
• Product Categories: ACETYLGROUP
• Mol File: 165544-13-8.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(2-methyl-1,3-dioxan-2-yl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2-methyl-1,3-dioxan-2-yl)- (9CI)(165544-13-8)
• EPA Substance Registry System: Ethanone, 1-(2-methyl-1,3-dioxan-2-yl)- (9CI)(165544-13-8)

Safety Data

• Hazardous Substances Data: 165544-13-8(Hazardous Substances Data)

Upstream product

• 431-03-8 dimethylglyoxal 
• 504-63-2 trimethyleneglycol 

Downstream Products

• 1569483-70-0 (E)-1-(2-methyl-1,3-dioxan-2-yl)-3-(4-nitrophenyl)prop-2-en-1-one 
• 1569483-72-2 (E)-1-(2-methyl-1,3-dioxan-2-yl)-3-phenylprop-2-en-1-one 
• 1569483-75-5 (E)-3-(4-methoxyphenyl)-1-(2-methyl-1,3-dioxan-2-yl)prop-2-en-1-one 

Relevant articles and documents

Synthesis of 2,5-dihydrofurans via alkylidene carbene insertion reactions

The insertion reaction of alkylidene carbenes is demonstrated to be an effective method for the synthesis of 2,5-dihydrofuran ring systems. The best results have been obtained on substrates containing electron-withdrawing substituents, which appear less prone to the competing rearrangement reaction. This insight has led to the development of a new method for the synthesis of the core structure of the squalestatin-zaragozic acid natural products.

Synthesis of 2,5-dihydrofurans via alkylidene carbene insertion reactions

The insertion of vinylidene carbenes into C-H bonds is an efficient method for the synthesis of 2,5-dihydrofurans. The methodology provides a convenient entry to the core structure of squalestatin/zaragozic acid natural products.