- Use of Silylated Formiates as Hydrosilane Equivalents
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The present invention relates to a method for preparing organic compounds of formula (I) by reaction between a silylated formiate of formula (II) and an organic compound in the presence of a catalyst and optionally of an additive. The invention also relates to use of the method for preparing organic compounds of formula (I) for the preparation of reagents for fine chemistry and for heavy chemistry, as well as in the production of vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, and pesticides.
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Paragraph 0514
(2021/09/26)
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- Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates
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An iron catalyst is shown for the first time to promote transfer hydrosilylation with silyl formates and is utilized for the silylation of alcohols. Attractive features of this protocol include the use of an earth-abundant transition-metal catalyst, mild reaction conditions, and the release of gases as the only byproducts (H 2 and CO 2).
- Godou, Timothé,Chauvier, Clément,Thuéry, Pierre,Cantat, Thibault
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supporting information
p. 2473 - 2477
(2017/10/26)
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