Nucleophilic substitution reactions of benzyl- and diphenylmethylphosphonamidic chlorides with amines: Competition between the usual SN2(P) mechanism and elimination-addition with an alkylideneoxophosphorane (phosphene) intermediate
The substitution reaction of PhCH2P(O)(NMe2)Cl with Me2NH or Et2NH in CHCI3 is very sensitive to the bulk of the nucleophile (≥ 200 times slower with Et2NH), affords only the product derive
Harger, Martin J. P.
p. 41 - 47
(2007/10/03)
Synthesis of Trisubstituted Vinyl Chlorides
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Crenshaw, Michael D.,Zimmer, Hans
p. 2782 - 2784
(2007/10/02)
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