Aluminum chloride catalyzed hydrosilylation of cyclopropanes with chlorodimethylsilane
Aluminum chloride can be utilized as an active catalyst for the highly regioselective hydrosilylation of 1-alkyl, 1-aryl, 1,1-dialkyl, and cyclic cyclopropanes with chlorodimethylsilane in hexane at room temperature.
Hydrosilylation of ortho- and para-substituted 2-phenylpropenes and ortho-, meta-, and para-alkoxysubstituted 3-phenylpropenes with chlorodimethylsilane in the presence of H2PtCl6 was effected. The resulting adducts were reacted with ethyntlmagnesium bromide to synthesize 2- and 3-arylpropyl(ethynyl)silanes. 2004 MAIK "Nauka/Interperiodica".
Yarosh,Zhilitskaya,Yarosh,Albanov,Voronkov
p. 1890 - 1894
(2007/10/03)
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