cas 17351-34-7, 14-Pentadecenoicacid | Articles data ｜lookchem

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17351-34-7

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Enzymatic Oxidative Tandem Decarboxylation of Dioic Acids to Terminal Dienes
The biocatalytic oxidative tandem decarboxylation of C7–C18dicarboxylic acids to terminal C5–C16dienes was catalyzed by the P450 monooxygenase OleT with conversions up to 29 % for 1,11-dodecadiene (0.49 g L–1). The sequential nature of the cascade was proven by the fact that decarboxylation of intermediate C6–C11ω-alkenoic acids and heptanedioic acid exclusively gave nonconjugated 1,4-pentadiene; scale-up allowed the isolation of 1,15-hexadecadiene and 1,11-dodecadiene; the system represents a short and green route to terminal dienes from renewable dicarboxylic acids.
Dennig, Alexander,Kurakin, Sara,Kuhn, Miriam,Dordic, Andela,Hall, Mélanie,Faber, Kurt
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p. 3473 - 3477
(2016/07/29)

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Chemical Properties

Boiling Point: 170-190 °C(Press: 2 Torr)
Density: 0.904±0.06 g/cm3(Predicted)
Storage Temp.:2-8°C
PKA: 4.78±0.10(Predicted)
PSA: 37.30000
LogP: 4.93820

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