Control of the "Superexchange" Interaction through Diphenyl Sulfide 4,4'-Diyl Magnetic Coupler by Changing the Oxidation State and Conformation of the Sulfur Atom
The exchange interaction between two triplet carbene centers through diphenyl sulfide 4,4'-diyl, its sulfoxide and sulfone analogs, and thiaxanthene 2,7-diyl coupling units was studied.Thse dicarbenes were generated by photolysis of the corresponding bisd
Effect of the Oxidation State of the Sulfur Atom on the Exchange Interaction between Two Triplet Carbene Units through Diphenyl Sulfide p,p'-Diyl Couplers
The exchange interaction between two triplet carbene centers through diphenyl sulfide p,p'-diyl and the corresponding sulfoxide coupling units was studied.While the former was found to by a ferromnagnetic coupler, the latter was found to by an antiferroma
Matsuda, Kenji,Yamagata, Takehiro,Iwamura, Hiizu
p. 1085 - 1086
(2007/10/03)
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