FREE-RADICAL CHLOROVINYLATION OF AROMATIC AND ALIPHATIC THIOLS
During the free-radical thiylation of trichloroethylene with organic thiols β,β-dichlorovinyl sulfides are formed in a single stage.The reaction of alkanethiols with tetrachloroethylene under analogous conditions leads to trichlorovinyl sulfides.Oxidation of β,β-dichlorovinyl sulfides with hydrogen peroxide in acetic acid leads to the corresponding β,β-dichlorovinyl sulfones.
Mirskova, A. N.,Martynov, A. V.,Voronkov, M. G.
p. 1766 - 1773
(2007/10/02)
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