- Generation and Chemistry of Cyclohexyloxy Radicals
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In this paper we report our work on cyclohexyloxy radicals from dicyclohexyl hyponitrite (CyON2OCy) and the related CyO sources dicyclohexyl peroxydicarbonate and dicyclohexyl peroxide (CyO2Cy), including the 13C and 1H NMR spectra of the radical sources, the kinetics of the DCHN decomposition over a wide range of temperature (followed by both UV and chemiluminescence), ESR spin-trapping studies, the kinetics of hydrogen atom abstraction from a variety of substrates by CyO, and the effect of CyO radical source on product composition.We have also investigated the effects of dissolved O2 on DCHN decomposition in cyclohexane and comment on the source of the observed chemiluminescence.
- Druliner, J. D.,Krusic, P. J.,Lehr, G. F.,Tolman, C. A.
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p. 5838 - 5845
(2007/10/02)
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