Synthesis of 2-acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl naphthalene: a product from the isomerisation of diels-alder adducts of both 5-methyl- and 6-methyl-2-acetyl-1,4-benzoquinone with 1,3-butadiene
2-Acetyl-5,8-dihydro-1,4-dihydroxy-3-methyl-naphthalene was synthesised via Diels-Alder addition of 2-acetyl-3-methyl-1,4-benzoquinone to buta-1,3-diene followed by enolisation. It was identical with material obtained by pyridine-induced acetyl migration
Ahmad, Faujan B. H.,Malcolm Bruce
p. 1263 - 1271
(2007/10/03)
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