- ORGANOMETALLARSINE. IX. t-BUTYL(TRIMETHYLELEMENT(IVB))ARSINE UND IHRE PENTACARBONYLCHROM-, -MOLEBDAEN- UND -WOLFRAM-KOMPLEXE
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Di-t-butylchloroarsine reacts with t-butyllithium to give tri-t-butylarsine and with trimethylchlorosilane-magnesium-tetrahydrofuran under formation of di-t-butyl(trimethylsilyl)arsine.Tris(trimethylsilyl)arsine was obtained in a similar way from arsenic trichloride with trimethylchlorosilane-magnesium-HMPA.Trimethylsilylarsines react with trimethylchloro-germane and -stannane to give the corresponding trimethyl-germyl- and stannyl-arsines.Organometalarsines react with hexacarbonyl-chromium, -molybdenum, or -tungsten with formation of pentacarbonyl(organometalarsine)- chromium, -molybdenum, or -tungsten complexes.NMR, IR, Raman, and He(I)-PE data of the new bulky arsine ligands and of some complexes are reported.
- Schumann, H.,Frank, U.,Mont, W. W. du,Marschner, F.
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- High luminescent semiconductor nai m crystal (by machine translation)
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A method of making a semiconductor nanocrystal can include contacting an M-containing compound with an X donor having the formula X(Y(R)3)3, where X is a group V element and Y is a group IV element.
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Paragraph 0060-0062
(2018/03/23)
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- Synthesis, structure reactivity of the arsaalkenes RAs=C(NMe2)2 [R = Me3Si, (η5-C5Me5)(CO)2Fe] and the 1,2-dihydroarsete (η5-C5Me5)(CO)2FeAs-C(NMe 2)=C(CO2Me)-CH(CO2Me)
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Reaction of equimolar amounts of thiuronium salt [(Me2N)2C-SMe]I (1) with LiAs(SiMe3)2 · 2 THF (2) afforded arsaalkene Me3SiAs=C(NMe2)2 (3). Combination of 3 with (η5-C5Me5)-(CO)2FeBr led to the formation of (η5-C5Me5)(CO)2-FeAs=C(NMe 2)2 (4). Reaction of the latter with dimethyl fumarate gave the 1,2-dihydroarsete (η5-C5Me5)(CO)2Fe-As-C(NMe 2)=C(CO2Me)-CH(CO2Me) (6). Compounds 3, 4, and 6 were characterized by means of spectroscopy (IR, 1H, 13C{1H}, 29Si{1H} NMR and mass spectrometry). The molecular structures of 4 and 6 were determined by X-ray diffraction analysis. VCH Verlagsgesellschaft mbH, 1996.
- Weber, Lothar,Kaminski, Olaf,Stammler, Hans-Georg,Neumann, Beate
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p. 223 - 226
(2007/10/02)
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