Isomerization of allylic silyl ethers catalyzed by ReO3(OSiR3) complexes
Efficient isomerization of allylic alcohols and allylic ethers at room temperature by rhenium (VII) oxo complexes is described. (C) 2000 Elsevier Science Ltd.
Bellemin-Laponnaz, Stéphane,Le Ny, Jean Pierre,Osborn, John A.
REGIO- AND STEREO-CHEMISTRY IN ALLYLATION OF ARYL GRINARD REAGENTS CATALYZED BY PHOSPHINE-NICKEL AND -PALLADIUM COMPLEXES
Nickel and palladium complexes with the 1,1'-bis(diphenylphosphino)ferrocene ligand effectively catalyze regioselective cross-coupling of allylic ethers such as 1- or 3-methyl-2-propenyl silyl ethers with aryl-Grinard reagents, where the nickel catalyst l