5,6,7,8-Tetrahydroquinolines. Part 6. Silylation vs. Thioamidation in the Reaction of Silyl Isothiocyanates with Organometallics: Influence of the Solvent and of the Substituent on Silicon.
The influence of a number of variables on carbophilic vs. silicophilic attack by 8-lithio-3-methyl-5,6,7,8-tetrahydroquinoline on silyl isothiocyanates is reported.In general carbophilic attack (i.e. thiomidation) is favoured in solvents of low polarity a
Crossley, Roger,Shepherd, Robin G.
p. 1917 - 1920
(2007/10/02)
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