179264-44-9Relevant articles and documents
Terpyridine-platinum(ii) acetylide complexes bearing pendent coordination units
Ziessel, Raymond,Diring, Stephane,Retailleau, Pascal
, p. 3285 - 3290 (2007/10/03)
Platinum(ii) complexes bearing various alkyne-pyrene, alkyne-4′-terpyridine and alkyne-dibutoxyphenylacetylide-terpyridine units were constructed in a step-by-step procedure based on copper-promoted cross-coupling reactions with preconstructed modules; formation of bis(ligand) complexes of Fe(ii) and Zn(ii) by binding of the pendent terpyridine units provided heterotrinuclear derivatives, all of which exhibit highly structured absorption features in solution and display a rich electrochemistry due to the presence of various redox active modules. The Royal Society of Chemistry 2006.
The preparation and some properties of substituted phenylene-ethynylene and phenylenebuta-1,3-diynylene polymers
Pelter, Andrew,Jones, D. Elfyn
, p. 2289 - 2294 (2007/10/03)
Syntheses are described for the preparation of a variety of diynes which are converted to high molecular weight substituted arylenebuta-1,3-diynylene polymers by oxidative coupling and to high molecular weight substituted arylene-ethynylene polymers by Pd(II) catalysed cross coupling reactions. The products tend to be insoluble in normal organic solvents. Doping with ferric chloride produces significant changes in conductivity but these are less than those produced on equivalently substituted thienylene-phenylene polymers.