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Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)praseodymium(III), commonly known as PR(FOD)3, is a lanthanide β-diketone complex that serves as an NMR shift reagent. It is characterized by its light green crystalline powder form and is known for its unique properties in chirality determination.

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  • 2,8,13-tri-tert-butyl-4,10,15-tris(1,1,2,2,3,3,3-heptafluoropropyl)-1λ3,5λ3,7λ3,11λ3,12λ3,16λ3-hexaoxa-6-praseodymaspiro[5.5 .5 ]hexadeca-1,4,7,10,12,15-hexaene

    Cas No: 17978-77-7

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  • 17978-77-7 Structure
  • Basic information

    1. Product Name: PR(FOD)3
    2. Synonyms: praseodymium,tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato-o,o;RONDEAU'S REAGENT;RESOLVE-AL(TM) PRFOD;PRASEODYMIUM(FOD);PRASEODYMIUM (FOD)3;PRASEODYMIUM/HEPTAFLUORODIMETHYL-OCTANEDIONE COMPLEX;PRASEODYMIUM III 6,6,7,7,8,8,8-HEPTA-FLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATE;PRASEODYMIUM(III) TRIS(6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATE)
    3. CAS NO:17978-77-7
    4. Molecular Formula: C30H30F21O6Pr
    5. Molecular Weight: 1026.43
    6. EINECS: 241-902-6
    7. Product Categories: Classes of Metal Compounds;Pr (Praseodymium) Compounds;Transition Metal Compounds;Other Metal
    8. Mol File: 17978-77-7.mol
  • Chemical Properties

    1. Melting Point: 215-219 °C(lit.)
    2. Boiling Point: 130°C 0,01mm
    3. Flash Point: 75.5°C
    4. Appearance: light green/Powder
    5. Density: g/cm3
    6. Vapor Pressure: 0.0812mmHg at 25°C
    7. Refractive Index: N/A
    8. Storage Temp.: N/A
    9. Solubility: Soluble in hexane, methanol, tetrahydrofuran.
    10. Sensitive: Hygroscopic
    11. CAS DataBase Reference: PR(FOD)3(CAS DataBase Reference)
    12. NIST Chemistry Reference: PR(FOD)3(17978-77-7)
    13. EPA Substance Registry System: PR(FOD)3(17978-77-7)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: 36/37/38
    3. Safety Statements: 24/25
    4. WGK Germany: 3
    5. RTECS:
    6. TSCA: No
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 17978-77-7(Hazardous Substances Data)

17978-77-7 Usage

Uses

Used in Analytical Chemistry:
PR(FOD)3 is used as a chirality probe for determining the enantiomeric purity of biological amino alcohols. It facilitates ligand-to-ligand chirality transfer, allowing for the differentiation between enantiomers through NMR spectroscopy.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, PR(FOD)3 is utilized as a tool for the development and quality control of chiral drugs. Its ability to distinguish between enantiomers is crucial for ensuring the safety and efficacy of medications, as different enantiomers can have varying biological activities.
Used in Research and Development:
PR(FOD)3 is employed in academic and industrial research settings for the study of chiral compounds and the development of new methods for enantiomeric analysis. Its use in NMR spectroscopy provides valuable insights into the structure and properties of chiral molecules, contributing to advancements in various scientific fields.

Check Digit Verification of cas no

The CAS Registry Mumber 17978-77-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,9,7 and 8 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 17978-77:
(7*1)+(6*7)+(5*9)+(4*7)+(3*8)+(2*7)+(1*7)=167
167 % 10 = 7
So 17978-77-7 is a valid CAS Registry Number.
InChI:InChI=1/3C10H11F7O2.Pr/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;

17978-77-7 Well-known Company Product Price

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  • Alfa Aesar

  • (A14166)  Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)praseodymium(III), 99%   

  • 17978-77-7

  • 1g

  • 356.0CNY

  • Detail
  • Alfa Aesar

  • (A14166)  Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)praseodymium(III), 99%   

  • 17978-77-7

  • 5g

  • 1411.0CNY

  • Detail

17978-77-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name PR(FOD)3

1.2 Other means of identification

Product number -
Other names PRASEODYMIUM (FOD)3

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:17978-77-7 SDS

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