The Reactivity of Silyl Ethers to the Swern Reagent
The activated Me2SO reagent , 'Swern reagent'> oxidises the trimethylsilyl ethers of primary and secondary alcohols directly to the corresponding carbonyl compound.Useful selectivity is possible where competing ether groups possess large differences of steric hindrance.Dimethyl-t-butylsilyl ethers are unaffected by this reagent.
Afonso, Carlos M.,Barros, M. Teresa,Maycock, Christopher D.
p. 1221 - 1224
(2007/10/02)
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