cas 182565-27-1, 4-FLUORO-ALPHA-METHYLBENZYL ISOTHIOCYANATE | Articles data ｜lookchem

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182565-27-1

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Electrochemical Benzylic C(sp3)-H Isothiocyanation
Selective C(sp3)-H isothiocyanation represents a significant strategy for the synthesis of isothiocyanate derivatives. We report herein an electrochemical benzylic isothiocyanation in a highly chemo- and site-selective manner under external oxidant-free conditions. The high chemoselectivity is attributed to the facile in situ isomerization of benzylic thiocyanates to isothiocyanates. Notably, the method exhibits high functional group compatibility and is suitable for late-stage functionalization of bioactive molecules.
Guo, Weisi,Li, Ming,Li, Yufeng,Wang, Tao,Wen, Lirong,Zhang, Shanxue
supporting information
p. 1742 - 1746
(2022/03/14)

Novel selective thiadiazine DYRK1A inhibitor lead scaffold with human pancreatic β-cell proliferation activity
The Dual-Specificity Tyrosine Phosphorylation-Regulated Kinase 1A (DYRK1A) is an enzyme that has been implicated as an important drug target in various therapeutic areas, including neurological disorders (Down syndrome, Alzheimer's disease), oncology, and
Kumar, Kunal,Man-Un Ung, Peter,Wang, Peng,Wang, Hui,Li, Hailing,Andrews, Mary K.,Stewart, Andrew F.,Schlessinger, Avner,DeVita, Robert J.
supporting information
p. 1005 - 1016
(2018/09/05)

Synthesis and antitumor activity of optically active thiourea and their 2-aminobenzothiazole derivatives: A novel class of anticancer agents
A novel series of optically active 2-aminobenzothiazole derivatives were synthesized by reaction of optically active amine (I) with thiophosgene to obtain optically active isothiocyanates (IIa-h) which on condensation with 4-fluoro-3-chloro aniline (III)
Manjula,Malleshappa Noolvi,Vipan Parihar,Manohara Reddy,Ramani, Vijay,Gadad, Andanappa K.,Singh, Gurdial,Gopalan Kutty,Mallikarjuna Rao
experimental part
p. 2923 - 2929
(2009/09/30)

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61290-52-6
1-[1-(4-Fluoro-phenyl)-ethyl]-3-(2-hydroxy-ethyl)-thiourea

Chemical Properties

Appearance/Colour :colorless liquid
Boiling Point: 248.4 °C at 760 mmHg
Flash Point:104 °C
Density: 1.1 g/cm³
Storage Temp.:Keep Cold
Refractive Index: 1.562
Sensitive: Moisture Sensitive/Lachrymatory
BRN: 6123780
PSA: 44.45000
LogP: 2.98950

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