Palladium-catalyzed tandem alkenyl and aryl C-N bond formation: A cascade N-annulation route to 1-functionalized indoles
(Chemical Equation Presented) A single tandem operation allows rapid access to a variety of substituted N-functionalized indoles. The nitrogen atom of the indole nucleus is incorporated through Pd-catalyzed aryl and alkenyl C-N bond-forming reactions (see scheme; dba = dibenzylideneacetone). Amine, aniline, amide, carbamate, and sulfonamide functional groups can be introduced efficiently.
Willis, Michael C.,Brace, Gareth N.,Holmes, Ian P.
p. 403 - 406
(2007/10/03)
ON THE REDUCTION OF vic-DIOXOPYRROLOINDOLES WITH LITHIUM ALUMINUM HYDRIDE
Dioxopyrrolindoles and their structural analogues, diazapropellanediones were reduced by lithium aluminum hydride affording their hydrogenated derivatives (1) and (2), each of them representing a mixture of diastereomers.Under equal reaction
Kollenz, Gert,Xi, Chang He
p. 1603 - 1614
(2007/10/02)
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