18435-22-8

Basic information

• Product Name: Tetradecane, 3-methyl-
• Synonyms: Tetradecane, 3-methyl-
• CAS NO: 18435-22-8
• Molecular Formula: C₁₅H₃₂
• Molecular Weight: 212.41
• Mol File: 18435-22-8.mol

Chemical Properties

• Melting Point: -32°C
• Boiling Point: 266.3°C
• Flash Point: 89.5°C
• Appearance: /
• Density: 0.7682
• Vapor Pressure: 0.0153mmHg at 25°C
• Refractive Index: 1.4313
• CAS DataBase Reference: Tetradecane, 3-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Tetradecane, 3-methyl-(18435-22-8)
• EPA Substance Registry System: Tetradecane, 3-methyl-(18435-22-8)

Safety Data

• Hazardous Substances Data: 18435-22-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H32/c1-4-6-7-8-9-10-11-12-13-14-15(3)5-2/h15H,4-14H2,1-3H3

Upstream product

• 103677-70-9 dodecanoyl 2-methylbutyryl peroxide 
• 91-17-8 decalin 

Relevant articles and documents

Process for hydrogenation of carboxylic acids and derivatives to hydrocarbons

A process for hydrogenating a carboxylic acid and/or derivative thereof having a carboxylate group represented by the general formula R1COO-, which process comprises feeding hydrogen and the carboxylic acid and/or derivative thereof to a reactor and maintaining conditions within the reactor such that hydrogen reacts with the carboxylic acid and/or derivative thereof to produce a product stream comprising carbon dioxide, carbon monoxide, methane and hydrocarbons represented by general formulae R1H and R1CH3, characterised in that the molar ratio of R1H : R1CH3 is above a pre-determined value and/or the mole ratio of the sum of carbon dioxide, carbon monoxide and methane to carboxylate groups is above a pre-determined value.

SELECTIVE MIXED COUPLING OF CARBOXYLIC ACIDS (I). - ELECTROLYSIS, THERMOLYSIS AND PHOTOLYSIS OF UNSYMMETRICAL DIACYL PEROXIDES WITH ACYCLIC AND CYCLIC ALKYL GROUPS

14 unsymmetrical diacyl peroxides (R1CO2-O2CR2 with R1: undecyl; R2: e.g. methyl, propyl, pentyl, nonyl, 2-methylpropyl, 2-propyl, 2-pentyl, cyclopropyl, cyclobutyl, cyclohexyl) are prepared in 85 to 92 percent yield.Square pulse electrolysis of dodecanoyl octanoyl peroxide (1i) affords the unsymmetrical coupling product octadecane (4) in poor yield and selectivity.Thermolysis or photolysis in solution produces preferentially 4, but also considerable amounts of disproportionation products.At -78 deg C the neat peroxides are photolysed selectively to the mixed dimers.With straight chain and β-branched alkyl groups high yields are obtained (63 - 76 percent), with cycloalkyl groups medium yields (42 - 56 percent), and with α-branched diacyl peroxides moderate yields (20 - 33 percent).A comparison of the mixed Kolbe-electrolysis with the low temperature photolysis of the neat peroxide demonstrates the superiority of the latter method in small scale conversion with regard to yield and selectivity.