An aldehyde compound represented by the formula (1) is reacted with an organometallic compound represented by the formula (2) to give an alcohol compound represented by the formula (3), which is then subjected to deprotection of a hydroxyl group and production of aldehyde by acid hydrolysis. wherein R1 and R2 are each independently a hydroxyl-protecting group or R1 and R2 in combination show a hydroxyl-protecting group, R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a silyl group or R3 and R4 in combination show a cyclic alkyl group.
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Page/Page column 15
(2010/02/13)
Synthesis of racemic 3,5-?-benzylidene-2-deoxypentoses from 2-phenyl-1,3-dioxan-5-one hydrate
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Ulven, Trond,Sorbye, Karsten A.,Carlsen, Per H. J.
p. 1041 - 1044
(2007/10/03)
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