- Synthesis and Crystal Structure of Isonitroso(2-methylthiazol-4-yl)acetamide
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The synthesis and crystal structure of a new thiazole derivative, isonitroso(2-methylthiazol-4-yl)-acetamide are described. Crystals of this compound are rhombic, space group P 212121 with the unit cell parameters a 5226(1), b 11.464(2), c 13.378(3) A, V 801.5(3) A3, pcalc 1.535 g cm-3. The structure is refined until the divergence factors R1 0.028 and ωR2 0.074, basing on 2027 independent reflections with I > 2σ(I). Molecule is strongly nonplanar, the oxyme group having syn configuration in relation to the 4-thiazolyl substituent. Peculiarities of the crystal structure are discussed.
- Domasevich,Sieler
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p. 1326 - 1329
(2007/10/03)
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