- Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: Synthesis of siloxanols
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A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)2 or Cu(OAc)2/NHPI-catalyzed oxidation of hydride siloxanes using "green", commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).
- Arzumanyan, Ashot V.,Goncharova, Irina K.,Novikov, Roman A.,Milenin, Sergey A.,Boldyrev, Konstantin L.,Solyev, Pavel N.,Tkachev, Yaroslav V.,Volodin, Alexander D.,Smol'Yakov, Alexander F.,Korlyukov, Alexander A.,Muzafarov, Aziz M.
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supporting information
p. 1467 - 1471
(2018/04/12)
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- Synthesis and crystal structure of disiloxane-1,3-diols and disiloxane-1,1,3,3-tetraol
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1,3-Dimethyl- or 1,3-divinyl-1,3-di-t-butoxydisiloxane-1,3-diol and 1,3-diphenyldisiloxane-1,1,3,3-tetraol were synthesized by hydrolysis of the corresponding diisocyanatodisiloxanes and tetrachlorodisiloxane. The disiloxanediols were soluble in common or
- Suyama, Ken-ichi,Nakatsuka, Takanori,Gunji, Takahiro,Abe, Yoshimoto
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p. 2028 - 2035
(2007/10/03)
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