The right way to self-fuse bi- and terpyrenyls to afford graphenic cutouts
In this work, we subject bi- and terpyrenyls to selective fusion for formation of extended polycyclic aromatic hydrocarbons (PAHs). Connecting the pyrene units at 4-4′- or 1-4′-positions led to smooth formation of extended PAHs, achieved via cyclodehydrog
Lorbach, Dominik,Wagner, Manfred,Baumgarten, Martin,Muellen, Klaus
supporting information
p. 10578 - 10580
(2013/11/06)
OXIDATIVE COUPLING OF 9,10-DIHYDROPHENANTHRENE AND POLYNUCLEAR HYDROCARBONS BY ALUMINUM CHLORIDE-CUPRIC CHLORIDE
Products from the oxidative coupling of 9,10-dihydrophenanthrene and polynuclear hydrocarbons (phenanthrene and pyrene) with AlCl3-CuCl2 included the respective dehydro dimers and trimers, accompanied by higher oligomers.