188476-19-9

Basic information

• Product Name: Oxiranemethanol, 2,3,3-trimethyl-, (S)- (9CI)
• Synonyms: Oxiranemethanol, 2,3,3-trimethyl-, (S)- (9CI)
• CAS NO: 188476-19-9
• Molecular Formula: C6H12O2
• Molecular Weight: 0
• Mol File: 188476-19-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Oxiranemethanol, 2,3,3-trimethyl-, (S)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Oxiranemethanol, 2,3,3-trimethyl-, (S)- (9CI)(188476-19-9)
• EPA Substance Registry System: Oxiranemethanol, 2,3,3-trimethyl-, (S)- (9CI)(188476-19-9)

Safety Data

• Hazardous Substances Data: 188476-19-9(Hazardous Substances Data)

Upstream product

• 497-02-9 (E)-2-methyl-2-buten-1-ol 
• 563-79-1 2,3-Dimethyl-2-butene 

Relevant articles and documents

Synthesis, characterization and catalytic epoxidation properties of a new tellurotungstate(iv)-supported rhenium carbonyl derivative

A monomeric tellurotungstate(iv)-supported rhenium carbonyl derivative: Na2H2[(CH3)4N]6[Te2W20O70{Re(CO)3}2]·20H2O (1) has been successfully isolated and structurally characterized by single crystal X-ray diffraction crystallography, IR and UV-Vis spectroscopy, thermogravimetric analysis, etc. In particular, complex 1 could act as a efficient and reusable heterogeneous catalyst for selective epoxidation of various alkenes including different cycloalkenes, styrene derivatives, internal and long-chain alkenes. For example, cis-cyclooctene undergoes up to 98.2% conversion and >99% selectivity at 75 °C in acetonitrile with 30% H2O2 as an oxidant. Additionally, the electrocatalytic property of 1 for NO2? reduction was also investigated.

Asymmetric cis-Hydroxylation via Epoxydation-Carboxylation: A Formal Synthesis of (+)-Citreoviral

Asymmetric epoxydation of tiglyl alcohol combined with Pd(0) catalyzed conversion to the vicinal diol with retention of configuration provides an efficient asymmetric synthesis of a key intermediate to (+)-citreoviral and related compounds.