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(R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl is a chiral compound that serves as a ligand in asymmetric catalysis. It features a binaphthyl backbone and a phosphine group, which together contribute to its effectiveness as a chiral ligand for a range of metal-catalyzed organic reactions. (R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl is recognized for its ability to confer high levels of enantioselectivity in catalytic processes, making it a key component in the synthesis of pharmaceuticals, agrochemicals, and other fine chemicals.

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  • Phosphine,[(1R)-2'-(1-methylethoxy)[1,1'-binaphthalen]-2-yl]diphenyl- (9CI)

    Cas No: 189274-36-0

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  • 189274-36-0 Structure
  • Basic information

    1. Product Name: (R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl
    2. Synonyms: (R)-(+)-(diphenylphosphino)-2`-isopropoxy-1,1`-binaphthyl;[(1R)-2'-(1-Methylethoxy)[1,1'-binaphthalen]-2-yl]diphenylphosphine;(R)-(2'-Isopropoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine
    3. CAS NO:189274-36-0
    4. Molecular Formula: C35H29OP
    5. Molecular Weight: 496.58
    6. EINECS: N/A
    7. Product Categories: Chiral Reagents
    8. Mol File: 189274-36-0.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
    8. Solubility: N/A
    9. CAS DataBase Reference: (R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl(CAS DataBase Reference)
    10. NIST Chemistry Reference: (R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl(189274-36-0)
    11. EPA Substance Registry System: (R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl(189274-36-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 189274-36-0(Hazardous Substances Data)

189274-36-0 Usage

Uses

Used in Pharmaceutical Synthesis:
(R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl is used as a chiral ligand in the synthesis of pharmaceuticals for its ability to induce high enantioselectivity, which is crucial for producing the desired enantiomer of a drug with specific biological activity.
Used in Agrochemical Production:
In the agrochemical industry, (R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl is utilized as a chiral ligand to ensure the selective synthesis of enantiomerically pure active ingredients, which is essential for the effectiveness and safety of agrochemicals.
Used in the Synthesis of Fine Chemicals:
(R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl is employed as a chiral ligand in the synthesis of fine chemicals to achieve the high enantioselectivity required for the production of specialty chemicals with specific applications.
Used in Material Development:
(R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl is used as a component in the development of new materials, leveraging its chiral properties to influence the physical and chemical characteristics of the materials produced.
Used in Organic Light-Emitting Diodes (OLEDs):
In the field of OLEDs, (R)-(+)-(Diphenylphosphino)-2'-isopropoxy-1,1'-binaphthyl is studied for its potential applications, possibly due to its ability to enhance the performance or efficiency of these devices through its chiral and electronic properties.

Check Digit Verification of cas no

The CAS Registry Mumber 189274-36-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,9,2,7 and 4 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 189274-36:
(8*1)+(7*8)+(6*9)+(5*2)+(4*7)+(3*4)+(2*3)+(1*6)=180
180 % 10 = 0
So 189274-36-0 is a valid CAS Registry Number.

189274-36-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (R)-(2'-Isopropoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:189274-36-0 SDS

189274-36-0Downstream Products

189274-36-0Relevant articles and documents

Optically active tertiary phosphine compound and transition metal complex using the same as ligand

-

, (2008/06/13)

A phosphine compound represented by formula (I): STR1 wherein Ph represents a phenyl group; and R represents a lower alkyl group or --OR1, wherein R1 represents a hydrogen atom, a cycloalkyl group having from 5 to 7 carbon atoms, or

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