19165-06-1

Basic information

• Product Name: 2-deoxy-L-fucose
• Synonyms: 2-deoxy-L-fucose
• CAS NO: 19165-06-1
• Molecular Formula: C₆H₁₂O₄
• Molecular Weight: 148.16
• Mol File: 19165-06-1.mol

Chemical Properties

• Boiling Point: 365.9°Cat760mmHg
• Flash Point: 189.3°C
• Appearance: /
• Density: 1.249g/cm³
• Vapor Pressure: 7.73E-07mmHg at 25°C
• Refractive Index: 1.494
• CAS DataBase Reference: 2-deoxy-L-fucose(CAS DataBase Reference)
• NIST Chemistry Reference: 2-deoxy-L-fucose(19165-06-1)
• EPA Substance Registry System: 2-deoxy-L-fucose(19165-06-1)

Safety Data

• Hazardous Substances Data: 19165-06-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H12O4/c1-4(8)6(10)5(9)2-3-7/h3-6,8-10H,2H2,1H3/t4-,5-,6+/m0/s1

Upstream product

• 104048-37-5 ((E)-5-Propenyl)-4,5-dihydro-isoxazole 
• 104048-44-4 (1R,2S)-(S)-1-(4,5-Dihydro-isoxazol-5-yl)-propane-1,2-diol 
• 104048-44-4 (1S,2R)-(S)-1-(4,5-Dihydro-isoxazol-5-yl)-propane-1,2-diol 
• 67308-47-8 methyl-(α-D-xylo-2-deoxy-hexopyranoside) 
• 897959-06-7 methyl-[tris-O-(toluene-4-sulfonyl)-α-D-xylo-2-deoxy-hexopyranoside] 
• 14711-68-3 methyl-[bis-O-(toluene-4-sulfonyl)-α-D-xylo-2,6-dideoxy-hexopyranoside] 
• 77210-24-3 methyl 2,6-dideoxy-α-D-xylo-hexopyranoside 

Relevant articles and documents

Anthraquinone glycosides from marine Streptomyces sp. strain

Two new anthraquinone glycosides Strepnoneside A (1) and Strepnoneside B (2), together with Chromomycin A3 (3), were isolated from cultures of the marine Streptomyces sp. strain. The structures were elucidated on the basis of NMR spectroscopic and mass spectrometry data. Compound 3 exhibited cytotoxic activities against HCT 116 cell lines (IC50 = 300 ± 11 pM).

SILYL NITRONATES AND NITRILE OXIDES IN ORGANIC SYNTHESIS. A NOVEL ROUTE TO D,L-DEOXYSUGARS. USE OF ALUMINIUM OXIDE AS SOLID PHASE BASE FOR GENERATION OF NITRILE OXIDES FROM HYDROXIMIC ACID CHLORIDES

Novel methodology is developed for a three step synthesis of deoxyaldoses and deoxyketoses. 1.Regioselective addition of silyl nitronate or nitrile oxide to a diene. 2.Stereospecific hydroxylation of the double bond. 3.Unmasking of the aldol moiety by catalytic reduction of the 2-isoxazoline.The syntheses of D.L-deoxyribose, D,L-oleose, D,L-digitoxose, D,L-2-deoxygalactose, 1,3-dideoxyfructose, 3-deoxyfructose etc. are described.Basic aluminium oxide is introduced as a solid phase base for the one step synthesis of 2-isoxazolines from aldoximes and olefins.An X-ray diffraction study of compound 13c verifies the stereochemical assignments.