Isomerization of linear to angular [3]phenylene and PAHs under flash vacuum pyrolysis conditions
(matrix presented) Flash vacuum pyrolysis (FVP) of linear [3]phenylene affords its angular counterpart and the same mixture of polycyclic aromatic hydrocarbon isomers as that observed on FVP of angular [3]phenylene. A mechanism, supported by a 13C labeling study, is proposed to explain these results.
Dosa, Peter I.,Schleifenbaum, Andreas,Vollhardt, K. Peter C.
p. 1017 - 1020
(2007/10/03)
CYCLOPENTAFLUORANTHENE: ACEFLUORANTHYLENE
Cyclopentafluoranthene (1, acefluoranthylene) is obtained by Flash Vacuum Thermolysis of 3-(1-chloroethenyl)fluoranthene (4).The electronic properties (cyclic voltammetry, UV/Vis and fluorescence) of 1 are markedly affected by cyclopenta-fusion.
Sarobe, Martin,Snoeijer, Judith D.,Jenneskens, Leonardus W.,Slagt, Martijn Q.,Zwikker, Jan W.