Conformational energies of perfluoroalkanes. 5. Dipole moments of H(CF2)nH and H(CF2)nI
Dielectric and refractive index increments at 25°C are reported for some α,ω-dihydroperfluoroalkanes and α-hydro-ω-iodoperfluoroalkanes in benzene and CCl4. Similar measurements on perfluorocyclohexane and perfluoro-n-hexane are used to deduce effective atomic polarizations for fluorocarbons in solution. The dipole moments obtained lead to a somewhat smaller characteristic ratio for the perfluoroalkane chain than had earlier been estimated by Bates and Stockmayer.
Matsuo, Keizo,Stockmayer, Walter H.
p. 3307 - 3311
(2007/10/02)
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