LaCl3·7H2O/NaI/benzyl alcohol: A novel reagent system for regioselective hydration of glycals: Application in the synthesis of 1,6-dideoxynojirimycin
Glycals can be readily hydrated using the LaCl3·7H2O/NaI/PhCH2OH reagent system. In one case, having an exo methylene group, such hydration gives an intermediate which is readily converted into 1,6-dideoxynojirimycin, a potential enzyme inhibitor.
Rani, Shikha,Agarwal, Aditi,Vankar, Yashwant D.
p. 5001 - 5004
(2007/10/03)
A stereoselective synthesis of 1,6-deoxynojirimycin by double-reductive amination of dicarbonyl sugar
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Dhavale,Saha,Desai
p. 7482 - 7484
(2007/10/03)
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