Constituents of Eupomatia Species. VII. Dienone-Phenol and Dienol-Benzene Rearrangements in the Eupodienone-1 Series
Rearrangement of eupodienone-1 and derivatives, including certain dienols, under a variety of acidic conditions produced dibenzocyclooctene derivatives.Spectroscopic evidence and chemical degradation showed that in the rearrangements alkyl rather than aryl group migration had occured.The stereochemistry of the products is discussed.
Bowden, Bruce F.,Read, Roger W.,Taylor, Walter C.
p. 799 - 817
(2007/10/02)
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