A versatile hexadiene synthesis by decarboxylative sp3-sp 3 coupling/cope rearrangement
Have it both ways: The palladium-catalyzed decarboxylative coupling of esters with two allyl groups results in kinetic allylation at a position α to electron-withdrawing groups. Tandem allylation/Cope rearrangement provides access to γ-coupling products (
Waetzig, Shelli R.,Rayabarapu, Dinesh K.,Weaver, Jimmie D.,Tunge, Jon A.
p. 4977 - 4980
(2007/10/03)
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