19816-73-0Relevant articles and documents
Lipase catalyzed synthesis of peroxycarboxylic acids and lipase mediated oxidations
Bjorkling,Frykman,Godtfredsen,Kirk
, p. 4587 - 4592 (1992)
Lipase catalyzed synthesis of long chain peroxycarboxylic acids from hydrogen peroxide and free carboxylic acid was investigated. A 51% yield of peroxytetradecanoic acid was achieved when using a two phase system of toluene and water. The peroxy acids thus formed were applied for in situ oxidation of alkenes, in general leading to high yields of the corresponding epoxide. For example, a quantitative yield of cyclohexene oxide and a 94% yield of 1-hexadecene oxide was achieved in a solvent-free process.
Thermal decomposition of aliphatic peroxy acids
Dutka,Zagorskaya,Dutka, Yu. V.,Savitskaya
experimental part, p. 353 - 357 (2011/08/05)
The thermal decomposition reactions of aliphatic peroxy acids containing from 8 to 16 carbon atoms in a molecule were studied. It was found that the carbon radical length had no effect on the thermal stability of peroxide groups. The apparent rate constants of thermolysis of peroxydecanoic acid in various solvents and the activation energies of the test reaction were found. The thermal degradation of peroxy acids involved secondary reactions of induced chain degradation in addition to the primary homolysis of the peroxide group. The rate constants of induced chain degradation were found.
NOUVEAUX DECONTAMINANTS. DESTRUCTION CHIMIQUE TOTALE, RAPIDE ET DOUCE D'INSECTICIDES ET DE TOXIQUES DE GUERRE PAR LES PERACIDES
Lion, C.,Charvy, C.,Hedayatullah, Mir,Bauer, P.,Sentenac-Roumanou, H.,et al.
, p. 127 - 133 (2007/10/02)
Peroxyacids RCOOOH (R = n C7H15 to n C13H27) are very good decontamination reagents.Paraoxon (O,O-diethyl O-p nitrophenyl phosphate), VX and HD (2,2'-dichlorodiethylsulfide) react for example, with perdodecanoic acid, completely in a few seconds.The reaction rate is enhanced by micellar catalysis.
