198491-04-2

Basic information

• Product Name: (R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2)
• Synonyms: (R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2);(S)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(S)-(1,1'-BINAPHTHYL-2)
• CAS NO: 198491-04-2
• Molecular Formula: C46H36O2Zr 10*
• Molecular Weight: 712
• Mol File: 198491-04-2.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2)(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2)(198491-04-2)
• EPA Substance Registry System: (R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2)(198491-04-2)

Safety Data

• Hazardous Substances Data: 198491-04-2(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Industry:
(R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2) is used as a catalyst for the synthesis of chiral molecules and pharmaceuticals. Its enantioselective properties allow for the creation of specific isomers, which are crucial in the development of effective and targeted drugs.
Used in Chemical Research:
In the field of chemical research, (R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2) is utilized as a catalyst for various organic reactions. Its ability to facilitate enantioselective reactions makes it a valuable tool in the development of new catalytic systems for organic synthesis, contributing to the advancement of chemical processes and methodologies.
Used in Asymmetric Catalysis:
(R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2) is employed as a catalyst in asymmetric catalysis, a branch of chemistry that focuses on the selective synthesis of chiral compounds. (R)-BIPHENYL-(3,4-DIMETHYL-1-CYCLOPENTADIENYL)-ZIRCONIUM(IV)-(R)-(1,1'-BINAPHTHYL-2)'s chiral nature enables the production of specific enantiomers, which are essential in various applications, including the creation of pharmaceuticals and other specialty chemicals.

Upstream product

• 602-09-5 (R)-binaphthol 
• 221196-95-8 [2,2'-biphenyldiylbis(3,4-diphenyl-1-cyclopentadienyl)]zirconium dimethyl 

Relevant articles and documents

Asymmetric thermal transformation, a new way to enantiopure biphenyl- bridged titanocene and zirconocene complexes: Efficient catalysts for asymmetric imine hydrogenation

Enantiopure biphenyl-bridged titanocene and zirconocene complexes were obtained, by an asymmetric thermal transformation of the binaphthol complexes formed from the metallocene racemates and subsequent transformation to the corresponding dichlorides, in practically quantitative yields. Increased rates of this transformation in the presence of O2 gas or TEMPO indicate a radical reaction mechanism. The biphenyl-bridged titanocene enantiomers give rise to an efficient asymmetric catalysis for the hydrogenation of cyclic and noncyclic imines.

Ansa-metallocene derivatives XXXIX: Biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium: Syntheses, crystal structures and enantioseparation

Chiral, biphenyl-bridged metallocene complexes of general type biph(3,4-R2C5H2)2MCl2 (biph = 1,1′-biphenyldiyl) were synthesized and characterized. For the dimethyl-substituted titanocenes and zircono