Accelerated reduction and solubilization of elemental sulfur by 1,2-aminothiols
Nucleophilic 1,2-aminothiol compounds readily reduce typically-insoluble elemental sulfur to polysulfides in both water and nonpolar organic solvents. The resulting anionic polysulfide species are stabilized through hydrogen-bonding interactions with the proximal amine moieties. These interactions can facilitate sulfur transfer to alkenes.
Stoffel, Jonathan T.,Riordan, Kimberly T.,Tsui, Emily Y.
supporting information
p. 12488 - 12491
(2021/12/04)
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