The effects of N-methylation on the enantioselectivity of catalysis by cyclo[(R)-His-(R)-Phe]
The cyclic dipeptide cyclo[(R)-His-(R)-Phe] 1 has been known since 1981 to catalyze the enantioselective formation of cyanohydrins from aldehydes and HCN. Although 1 has proved to be very effective in the production of optically active cyanohydrins, the p
Thoen, Jason C.,Lipton, Mark A.
p. 3947 - 3954
(2007/10/03)
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