- Charge distribution within hypercarbon-halogenated 1-Ph-2-X-1,2-dicarba- closo-dodecaboranes, (X = F, Cl, Br, I): A dipole moment and computational study
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Vector analyses of experimental dipole moments of a series of halogenated 1-Ph-2-X-1,2-dicarba-closododecaboranes, (X = F, Cl, Br, I) combined with theoretical calculations show that there are intramolecular contacts between heavy halogens (Br and I) and the benzene ring, whereas this attraction is absent for F and Cl.
- Hnyk, Drahomír,V?ete?ka, Václav,Dro?, Ladislav
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- Investigations on the reactivity of Li/Cl phosphinidenoid tungsten complexes toward various iodine compounds
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Reactivity studies of Li/Cl phosphinidenoid W(CO)5 complexes 2a,b toward various iodine compounds are reported. Transiently generated complexes 2a,b yielded no selective reactions with 3-, 9-, and 9,12-diiodo o-carbaboranes 3a-c, whereas clean transfer-io
- Streubel, Rainer,Oezbolat-Schoen, Aysel,Bode, Maren,Daniels, Joerg,Schnakenburg, Gregor,Teixidor, Francesc,Vinas, Clara,Vaca, Albert,Pepiol, Ariadna,Farras, Pau
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p. 6031 - 6035
(2010/03/04)
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