Functionalized p-phenylene sulfides synthesis of new molecular wires
Molecular wires containing p-phenylene sulfide units were synthesized. They could be used in material sciences and in supramolecular chemistry. Wires having 2 to 6 phenyl rings were functionalized at one end by an SH or SMe group, and at the other end, by an OH, OMe or OiPr groups. Formation of Ar-S bonds in the chain was achieved by Pd- or Cu-catalyzed couplings of aromatic thiols with aromatic halides. Conditions for a clean chemoselective deprotection of thiols from thiomethyl groups were developed.
Pinchart, Alain,Dallaire, Carol,Gingras, Marc
p. 543 - 546
(2007/10/03)
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