cas 205443-23-8, (R)-1-Benzyl-azetidine-2-carboxylic acid methyl ester | Articles data ｜lookchem

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205443-23-8

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Highly efficient and enantioselective biotransformations of racemic azetidine-2-carbonitriles and their synthetic applications
(Chemical Equation Presented) Catalyzed by the Rhodococcus erythropolis AJ270 whole cell catalyst in neutral aqueous buffer at 30 °C, a number of racemic 1-benzylazetidine-2-carbonitriles, trans-1-benzyl-4-methylazetidine-2- carbonitrile, and 1-benzyl-2-m
Leng, Dong-Hui,Wang, De-Xiang,Pan, Jie,Huang, Zhi-Tang,Wang, Mei-Xiang
experimental part
p. 6077 - 6082
(2009/12/26)

Enzymatic resolution of methyl N-alkyl-azetidine-2-carboxylates by Candida antarctica lipase-mediated ammoniolysis
A facile method for the synthesis of optically active azetidine-2- carboxylic acid derivatives is presented Racemic N-alkylated azetidine esters are resolved by lipase from Candida antarctica in an ammoniolysis reaction, and both the S-amide and the R-ester are obtained with excellent stereoselectivity.
Starmans, Wim A. J.,Doppen, Roy G.,Thijs, Lambertus,Zwanenburg, Binne
p. 429 - 435
(2007/10/03)

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Chemical Properties

Boiling Point: 272.8±33.0 °C(Predicted)
Density: 1.153±0.06 g/cm3(Predicted)
PKA: 6.42±0.40(Predicted)
PSA: 29.54000
LogP: 1.37180

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