20634-62-2

Basic information

• Product Name: prop-2-yn-1-yl undec-10-enoate
• CAS NO: 20634-62-2
• Molecular Formula: C₁₄H₂₂O₂
• Molecular Weight: 222.3233
• Mol File: 20634-62-2.mol

Chemical Properties

• Boiling Point: 300.9°C at 760 mmHg
• Flash Point: 122.6°C
• Density: 0.918g/cm³
• Vapor Pressure: 0.00109mmHg at 25°C
• Refractive Index: 1.459
• CAS DataBase Reference: prop-2-yn-1-yl undec-10-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: prop-2-yn-1-yl undec-10-enoate(20634-62-2)
• EPA Substance Registry System: prop-2-yn-1-yl undec-10-enoate(20634-62-2)

Safety Data

• Hazardous Substances Data: 20634-62-2(Hazardous Substances Data)

Upstream product

• 2065-66-9 methyl-triphenylphosphonium iodide 
• 112-38-9 10-undecenoic acid 
• 107-19-7 propargyl alcohol 

Relevant articles and documents

Efficient Synthesis of Cyclic Carbonates from Unsaturated Acids and Carbon Dioxide and their Application in the Synthesis of Biobased Polyurethanes

Bio-derived furan- and diacid-derived cyclic carbonates have been synthesized in high yields from terminal epoxides and CO2. Furthermore, four highly substituted terpene-derived cyclic carbonates were isolated in good yields with excellent diastereoselectivity in some cases. Eleven new cyclic carbonates derived from 10-undecenoic acid under mild reaction conditions were prepared, providing the corresponding carbonate products in excellent yields. The catalyst system also performed the conversion of an epoxidized fatty acid n-pentyl ester into a cyclic carbonate under relatively mild reaction conditions (80 °C, 20 bar, 24 h). This bis(cyclic carbonate) was obtained in high yields and with different cis/trans ratios depending on the co-catalyst used. An allyl alcohol by-product was only observed as a minor product when bis(triphenylphosphine)iminium chloride was used as co-catalyst. Finally, two cyclic carbonates were used as building blocks for the preparation of non-isocyanate poly(hydroxy)urethanes by reaction with 1,4-diaminobutane.

Stereoselective nitration of olefins with tBuONO and TEMPO: Direct access to nitroolefins under metal-free conditions

Nitroolefins are essential elements for both synthetic chemistry and medicinal research. Despite significant improvements in nitration of olefin an efficient metal-free synthesis remains elusive so far. Herein, we disclose a new set of reagents to access nitroolefins in a single step under metal-free conditions. A wide range of olefins with diverse functionalities has been nitrated in synthetically useful yields. This transformation is operationally simple and exhibits excellent E-selectivity. Furthermore, site selective nitration in a complex setup makes this method advantageous.