208714-34-5Relevant articles and documents
?-C(sp2)-H alkylation of enamides using xanthate chemistry
Bertho, Sylvain,Dondasse, Isma?l,Retailleau, Pascal,Nicolas, Cyril,Gillaizeau, Isabelle
supporting information, p. 7129 - 7141 (2020/05/16)
Access to the ?-amino-?,?-unsaturated acyl scaffold was established by applying xanthate chemistry to enamides. This original ?-C(sp2)-H alkylation is regioselective and exhibits broad substrate scope and good functional group tolerance. The la
Palladium(II)-catalyzed direct alkenylation of nonaromatic enamides
Gigant, Nicolas,Gillaizeau, Isabelle
supporting information; experimental part, p. 3304 - 3307 (2012/07/31)
A mild and efficient method for the direct alkenylation of nonaromatic enamides was achieved through a palladium(II)-catalyzed C-H functionalization. The reaction scope includes cyclic and acyclic enamides and a range of activated alkenes. This approach represents the first successful direct C(3)-functionalization of nonaromatic cyclic enamides.