21089-34-9Relevant articles and documents
New acetylated flavone C-glycosides from Iris lactea
Whaley, Andrei K.,Ebrahim, Weaam,El-Neketi, Mona,Ancheeva, Elena U.,?zkaya, Ferhat Can,Pryakhina, Nina I.,Sipkina, Nadezhda U.,Luzhanin, Vladimir G.,Liu, Zhen,Proksch, Peter
, p. 2171 - 2173 (2017)
Chemical investigation of the aerial parts of Iris lactea afforded three new flavone C-glycosides including 4?-O-acetyl-embinin (1), 2?,4?-O-diacetyl-embinin (2) and 6″,4?-O-diacetyl-embinin (3) along with the known analogue embinin (4). Their structures
ACYLATED C-GLYCOSIDES OF Iris lactea
Pryakhina, N. I.,Sheichenko, V. I.,Blinova, K. F.
, p. 554 - 559 (2007/10/02)
From the epigeal part of Iris lactea two acylated C-glycosylflavones not described in the literature have been isolated.On the basis of chemical transformations, and the results of UV, IR, and NMR spectroscopy, the following structures hyve been established for them: substance (I) - 5-hydroxy-4',7-dimethoxyflavone 6-C-2)-x-acetyl-β-D-glucopyranoside> (diacetylembinin); substance (II) - 5-hydroxy-4',7-dimethoxyflavone 6-C-2)-D-glucopyranoside> (acetylembinin).The existence of rotamers for 6-C-glucoflavones has been established for the first time.
C-GLYCOSYLFLAVONES FROM SIPHONOGLOSSA SESSILIS
Hilsenbeck, Richard A.,Mabry, Tom J.
, p. 2215 - 2218 (2007/10/02)
Two known C-glycosylflavones, embinin and vicenin-2, and two new C-glycosylflavones, 8-C-glucosylapigenin 7,4'-dimethyl ether (isoembigenin) and2''-O-glucosyl-6-C-glucosylapigenin 7,4'-dimethyl ether (embinoidin) were obtained from Siphonoglossa sessilis.Key Word Index-Siphonoglossa sessilis; Acanthaceae; chemotaxonomy; C-glycosylflavones; embigenin; embinin; vicenin-2; mass spectrometry; permethylation; 1H NMR.