A concise stereoselective total synthesis of (-)-cephalosporolide D
A concise stereoselective total synthesis of eight-membered lactone (-)-cephalosporolide D has been derived from inexpensive and commercially available starting material (S)-propylene epoxide. This concise synthesis utilizes Grignard reaction, Noyori asym
Stereoselective total synthesis of cephalosporolide D
An efficient method for the synthesis of (-)-cephalosporolide D is established via successive enantioselective aldol and effective 8-membered ring lactone forming reactions.
Determination of Relative and Absolute Stereochemistry of Cephalosporolide D and Its Enantioselective Total Synthesis
An efficient method for the synthesis of (-)-cephalosporolide D was established via successive enantioselective aldol reaction and effective construction of 8-membered ring lactone moiety.