How iodide anions inhibit the phase-transfer catalyzed reactions of carbanions
The inhibitory effect of iodide anions on the phase-transfer catalyzed reactions of carbanions generated in liquid-liquid two-phase systems by aqueous NaOH is due to preferential location of these anions in the interfacial region of the two-phase system-organic phase/concd aqueous NaOH. In such situation, the basic activity of NaOH in this region is decreased and the equilibrium of deprotonation of the carbanion precursors is disfavoured.
Makosza, Mieczys?aw,Chesnokov, Alexey
p. 5925 - 5932
(2008/12/20)
Synthesis and antimycotic properties of 1 (2 alkyl 2 phenylethyl) 1H imidazoles
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Heeres,Backx,Van Cutsem
p. 1148 - 1155
(2007/10/05)
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