219561-95-2Relevant articles and documents
Palladium-Catalyzed Silylation of Aryl Bromides Leading to Functionalized Aryldimethylsilanols
Denmark, Scott E.,Kallemeyn, Jeffrey M.
, p. 3483 - 3486 (2007/10/03)
Equation presented. A mild and general palladium-catalyzed insertion of 1,2-diethoxy-1,1,2,2-tetramethyldisilane into a variety of aryl bromides affords the aryldimethylsilyl ethers in high yields. Hydrolysis of the ethers under pH-optimized conditions results in the exclusive formation of the desired aryldimethylsilanols.