TRIS(3,6-DIOXAHEPTYL)AMINE: A SUPERIOR COMPLEXING AGENT FOR DISSOLVING METAL REACTIONS
Commercially available tris(3,6-dioxaheptyl)amine (TDA-1) is an effective phase transfer catalyst for reactions with sodium-potassium alloy in tetrahydrofuran.Deoxygenation of acetates, dehalogenation, and hydrolysis of tosylates and mesylates proceed in high yield.The use of a deuterated alcohol during deoxygenation reactions leads to site-specific deuteration.
Bose, Ajay K.,Mangiaracina, Pietro
p. 2503 - 2506
(2007/10/02)
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