Synthesis and structure of a heterotrinuclear complex bridged by 2,6-bis(diphenylphosphino)pyridine, [Ir2Cu(CO)2Cl2(MeCN){μ-(Ph2P)2py}2](ClO4)
The complex Ir2(CO)2Cl2{μ-Ph2P)2py}2, which was synthesized from [Ir(cod)Cl]2 and (Ph2P)2py [(Ph2P)2py=2,6-bis(diphenylphosphino)pyridine)], reacted with [Cu(MeCN4)](ClO4) to form the heterotrinuclear complex [Ir2Cu(CO)2Cl2(MeCN){μ-(Ph2P)2py}2](ClO4), whose structure has been determined by X-ray crystallography.
Kuang, Shan-Ming,Zhang, Zheng-Zhi,Wang, Qi-Guang,Mak, Thomas C. W.
p. 493 - 496
(2008/10/08)
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