Carbohydrates to Carbocycles: A Synthesis of (-)-α-Pipitzol
A 2-deoxy-3-keto sugar derived from methyl α-D-mannopyranoside has been processed to give a multibranched-chain sugar which undergoes serial radical cyclization, affording a pyranosidodiquinane as the key intermediate.The diquinane moiety represents the B
Pak, Helen,Canalda, Isabel Iriepa,Fraser-Reid, Bert
p. 3009 - 3011
(2007/10/02)
A Reaction Mechanism Change in the Lewis Acid Catalyzed Perezone-Pipitzol Transformation
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Sanchez, I. H.,Yanez, R.,Enriquez, R.,Joseph-Nathan, P.
p. 2818 - 2819
(2007/10/02)
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