The first structural characterization of a binary P-N molecule: The highly energetic compound P3N21
(Chemical Equation Presented) An explosive mixture: The first structural characterization of a binary molecule of phosphorus and nitrogen is described. With the help of a new synthetic strategy, the phosphorus azide P 3N21 is prepared in pure form, and single crystals are isolated, enabling a structure determination by X-ray diffraction (see structure; P orange, N blue).
Goebel, Michael,Karaghiosoff, Konstantin,Klapoetke, Thomas M.
High energy density materials from azido cyclophosphazenes
Azido substituted cyclophosphazenes were prepared and their standard heats of formation were calculated based on experimentally determined heats of combustion. The Royal Society of Chemistry 2005.
Muralidharan,Omotowa, Bamidele A.,Twamley, Brendan,Piekarski, Crystal,Shreeve, Jean'ne M.
Reactions of Alkali-metal Azides with some Organophosphorus(V) Compounds
The reactions of Li or Na with some organophosphorus(V) compounds containing chloro-groups, including PCl5(py) (py = pyridine) and catechyl derivates of PCl5, have been investigated by I31IP n.m.r. spectroscopy.Several new azido-species have been
Dillon, Keith B.,Platt, Andrew W. G.,Waddington, Thomas C.
p. 2292 - 2295
(2007/10/02)
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